The number of molecules/ions that show linear geometry among the following is ______. SO2, BeCl2, CO2, N3 – , NO2, F2O, XeF2, NO2 + , I3 – , O3

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Published July 8, 2025
Chemistry
Inorganic Chemistry
Molecular Geometry
VSEPR Theory

Detailed Explanation

To find out which molecules or ions have linear geometry, we use the VSEPR (Valence Shell Electron Pair Repulsion) theory. This theory says that electron pairs around the central atom repel each other and arrange themselves to be as far apart as possible. The shape depends on the number of bonding pairs and lone pairs around the central atom.

Linear geometry happens when the central atom has two regions of electron density and no lone pairs, or when the lone pairs do not affect the shape (like in some ions). The bond angle in linear molecules is about 180 degrees.

Let's analyze each molecule/ion:

  • SO2: Central atom S has 3 regions (2 bonds + 1 lone pair) → bent shape, not linear.
  • BeCl2: Central atom Be has 2 bonds, no lone pairs → linear.
  • CO2: Central atom C has 2 double bonds, no lone pairs → linear.
  • N3– (azide ion): Resonance structure with linear shape.
  • NO2: Central atom N has 2 bonds + 1 lone pair → bent, not linear.
  • F2O: Central atom O has 2 bonds + 2 lone pairs → bent, not linear.
  • XeF2: Central atom Xe has 2 bonds + 3 lone pairs → linear.
  • NO2+: Central atom N has 2 bonds, no lone pairs → linear.
  • I3–: Central atom I has 2 bonds + 3 lone pairs → linear.
  • O3: Central atom O has 2 bonds + 1 lone pair → bent, not linear.

Counting the linear ones: BeCl2, CO2, N3–, XeF2, NO2+, I3– → total 6.

Simple Explanation (ELI5)

Imagine molecules as tiny shapes made by balls (atoms) connected by sticks (bonds). Some shapes are straight lines, like a straight stick, and some are bent or have angles. This question asks how many molecules or ions from a list look like a straight line. To find out, we use a simple rule called VSEPR theory, which helps us guess the shape based on how many bonds and lone pairs the central atom has. If the shape is straight, we say it has linear geometry.

Step-by-Step Solution

Step 1: Identify the central atom and count bonding pairs and lone pairs.

Step 2: Use VSEPR theory to predict shape.

Step 3: Check if the shape is linear (2 bonding pairs, 0 lone pairs or lone pairs arranged so shape remains linear).

Analyzing each:

  • SO2: Bent (not linear)
  • BeCl2: Linear
  • CO2: Linear
  • N3–: Linear
  • NO2: Bent (not linear)
  • F2O: Bent (not linear)
  • XeF2: Linear
  • NO2+: Linear
  • I3–: Linear
  • O3: Bent (not linear)

Number of linear molecules/ions = 6

Final answer: 6

Examples

Example 1

Water (H2O) is bent because oxygen has 2 bonds and 2 lone pairs.

Example 2

Carbon dioxide (CO2) is linear because carbon has 2 double bonds and no lone pairs.

Example 3

Beryllium chloride (BeCl2) is linear because beryllium has 2 bonds and no lone pairs.

Example 4

Azide ion (N3–) is linear due to resonance and arrangement of bonds.

Example 5

Xenon difluoride (XeF2) is linear because of 2 bonds and 3 lone pairs on xenon.

Visual Representation

References

  • [1]NCERT Chemistry Class 11 - The p-Block Elements
  • [2]J.D. Lee, Concise Inorganic Chemistry
  • [3]VSEPR Theory - LibreTexts Chemistry https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry
  • [4]Molecular Geometry - Khan Academy https://www.khanacademy.org/science/chemistry/chemical-bonds
  • [5]Inorganic Chemistry by Shriver and Atkins

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