**59.** Radius of the first excited state of Helium ion is given as: \( a_0 \rightarrow \) radius of first stationary state of hydrogen atom. Options: - (1) \( r = \frac{a_0}{2} \) - (2) \( r = \frac{a_0}{4} \) - (3) \( r = 4a_0 \) - (4) \( r = 2a_0 \)
Detailed Explanation
Key Ideas to Know
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Bohr Radius ()
The radius of the ground state () of the hydrogen atom. -
Bohr Model for Hydrogen-Like Species
For any one-electron ion (H, He⁺, Li²⁺ …) the radius of the orbit iswhere
• = principal quantum number (1, 2, 3 …)
• = nuclear charge (1 for H, 2 for He⁺, 3 for Li²⁺ …). -
First Excited State
Means (because the ground state is ).
Reasoning Chain a Student Should Follow
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Identify Z: For He⁺, .
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Identify n: First excited state → .
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Plug into Formula:
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Simplify:
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Match Option: Option (4) is the correct one.
Each step is chosen directly from Bohr’s radius formula, tailored to a hydrogen-like ion with higher nuclear charge.
Simple Explanation (ELI5)
Imagine Planets and Orbits
Think of an atom like a mini-solar system. The electron is the planet, and the nucleus is the Sun. For hydrogen, the very first circular path (orbit) has a special size called Bohr radius and we name it .
Now, a helium ion (He⁺) is like hydrogen but the Sun is twice as strong (because its charge is +2 instead of +1). When the planet jumps to the next bigger orbit (first excited state), you simply ask:
- How big is that orbit for hydrogen?
- How does a stronger Sun pull the planet closer?
The math answer says the new size is . So the helium planet’s first excited circle is exactly twice the Bohr radius.
Step-by-Step Solution
Step-by-Step Solution
- Write Bohr Radius Formula for Hydrogen-Like Ion
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Insert Helium Ion Data
Nuclear charge:
First excited state: -
Substitute
- Calculate
- Select Correct Option
Option (4) is correct.
Examples
Example 1
Satellite orbits: Higher gravitational pull (larger mass planet) shrinks orbit radii for the same orbital energy.
Example 2
Electron capture therapy: Heavy nuclei pull electrons closer, influencing transition energies in medical isotope design.
Example 3
Spectroscopy of ionized gases in nebulae: Sizes of orbits dictate emission line wavelengths when single-electron ions transition.